| Ti3SiC2耐氢氟酸腐蚀性研究 |
| Corrosion Resistance of Ti3SiC2 in Hydrofluoric Acid |
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| DOI：10.16253/j.cnki.37-1226/tq.2016.06.010 |
| 中文关键词: Ti3SiC2 二维碳化物晶体 耐腐蚀性 |
| 英文关键词:Ti3SiC2 two-dimensional transition metalcarbide crystal corrosion resistance |
| 基金项目:国家自然科学基金 (51472075, 51205111)，河南省科技创新人才计划 (134100510008)，河南理工大学科技创新团队 (T2013-4)，新型陶瓷与精细工艺国家重点实验室 (KF201313)。 |
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| 中文摘要: |
| 在Ar气氛中，以TiH2/Si/2TiC复合粉体为原料，利用无压烧结技术在1500°C下保温3 h成功制备出高纯Ti3SiC2，并利用氢氟酸对Ti3SiC2粉体进行刻蚀，研究其耐腐蚀性。XRD检测结果表明，在常压下Ti3SiC2样品经氢氟酸腐蚀前后的物相没有发生变化，且不随反应时间和温度的变化而发生变化。但是，扫描电镜图片显示样品中存在一些二维片层和腐蚀孔洞，这表明HF与Ti3SiC2发生了部分刻蚀反应。由于Ti3SiC2与酸的反应活性依赖于Si与酸的反应活性，而Si与HF在常压下反应较慢，因此Ti3SiC2与HF反应较困难。然而，Ti3SiC2与HF在180°C水热条件下则能完全反应，晶体结构遭到破坏，这表明Ti3SiC2在常温常压下对HF具有良好的耐腐蚀性，而在水热条件下Ti3SiC2易受HF的腐蚀。 |
| 英文摘要: |
| High pure Ti3SiC2 was synthesized from TiH2/Si/2TiC mixtures by pressureless sintering at 1500°C for 3 h in Ar atmosphere, and the hydrofluoric acid corrosion resistance of the prepared Ti3SiC2 was studied. The XRD results showed that the phase of Ti3SiC2 do not change after HF etched, and is little affected by reaction time and temperature in atmospheric pressure. However, there have some two-dimensional plates and corrosion holes in the samples as observed by SEM, suggesting that Ti3SiC2 partials were etched by HF. The low reaction rate between Ti3SiC2 and HF was due to the fact that the reactivity of Ti3SiC2 strongly depends on the reactivity of Si element with the acid, and silicon reacted with HF was very slowly at atmospheric pressure. However, the crystal structure of Ti3SiC2 was completely destroyed after hydrothermal reaction with HF at 180°C. This suggests that Ti3SiC2 have good hydrofluoric acid corrosion resistance at atmospheric pressure, whereas Ti3SiC2 is vulnerable at high temperature and high pressure. |
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